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27 Total Synthesis of Siomycin A, a Representative of the Thiostrepton Family of Peptide Antibiotics
[in Japanese]
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Mori Tomonori
,
Higashibayashi Shuhei
,
Goto Taiji
,
Kohno Mitsunori
,
Satouchi Yukiko
,
Shinko Kazuyuki
,
Suzuki Kengo
,
Suzuki Shunya
,
Tohmiya Hiraku
,
Hashimoto Kimiko
,
Nakata Masaya
… The segment A (the dehydropiperidine portion) was synthesized featuring the coupling between the azomethine ylide and the enantiopure sulfinimine, the subsequent stereoselective reduction of the 6-membered imine, and the regioselective dehydrogenation of the piperidin ring. …
天然有機化合物討論会講演要旨集 (48), 157-162, 2006-09-15
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