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Thio-Sugars.IV.Synthesis of Carbohydrate 1, 3-Glycol (Six-Membered) Thionocarbonates and Their Attempted O-S Rearrangement
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TSUDA Yoshisuke
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NOGUCHI Shinsuke
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NIINO Hideki
… Four six-membered cyclic thionocarbonates (two sec-sec and two prim-sec) were prepared and their radical-promoted O-S rearrangement reaction was examined. … The results revealed that the reaction in six-membered rings is difficult compared with the simple rearrangement in five-membered rings. …
Chemical & pharmaceutical bulletin 49(9), 1210-1213, 2001-09-01
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