Experimental Phase Equilibria in the Sr-Ca-Cu-O System Under Reduced Oxygen Atmosphere.

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  • Experimental Phase Equilibria in the Sr

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Abstract

Phase equilibria were studied in the Sr-Ca-Cu-O system by annealing samples at 1153K in Ar-O2 gas mixtures. The stability ranges of the oxide solid solutions were observed by X-ray diffraction measurements especially at 4 compositions in 12 gas mixtures. 4 sets of invariant 4-phase equilibrium and their oxygen partial pressure, P<sub>O2</sub>, were deduced from the surrounding 3-phase equilibria. The compositions of the related phases were evaluated by combining EDX analysis and the sample compositions. These results are compared with equilibrium calculations based on thermodynamic modelling.

Journal

  • Netsu Sokutei

    Netsu Sokutei 24 (2), 61-68, 1997

    The Japan Society of Calorimetry and Thermal Analysis

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