Phases and their Relations in the YO1.5-BaO(BaCO3)-SrO-CuO System.

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  • 酸化物超伝導体の合成と特性 YO1.5‐BaO(BaCO3)‐SrO‐CuO系における生成相と相関係
  • YO1.5 BaO BaCO3 SrO CuOケイ ニ オケル セイセイソウ

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Abstract

Phases and their relations in the Y01.5-BaO(BaCO3)-SrO-CuO system at 900°C in air have been studied mainly by the powder X-ray diffraction method. It was found that two new phases with compositions of (Y, Ba, Sr)2CuO2(CO3)y, Bs.s, and Y:Ba:Sr:Cu = 0.5:0.7:1.0:1.0, N, formed in this system. The newly found phase Bs.s was isostructural with the oxycarbonate Sr2CuO2(C03). The phase N has an orthorombic sturucture with lattice parameters of a=3.855Å, b=3.764Å, and c=12.69Å.

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