The Formation Process of Li-added Bi-2212 Phase.
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- Fujiwara Masashi
- Department of Applied Chemistry, Faculty of Engineering, Okayama University
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- Kikuchi Takeyuki
- Department of Applied Chemistry, Faculty of Engineering, Okayama University
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- Nagae Masahiro
- Department of Applied Chemistry, Faculty of Engineering, Okayama University
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- Nakajima Hideki
- Department of Applied Chemistry, Faculty of Engineering, Okayama University
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- Takada Jun
- Department of Applied Chemistry, Faculty of Engineering, Okayama University
Bibliographic Information
- Other Title
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- 酸化物超伝導体の合成と特性 Li添加Bi‐2212相の生成過程
- Li テンカ Bi 221 2ソウ ノ セイセイ カテイ
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Abstract
Effects of the Li-addition to the Bi-2212 phase on the formation process and the superconductive properties were studied for the samples with the nominal compositions of Bi:Sr:Ca:Cu:Li=2:1.5 :1.5:2:x(x=0 to 0.6). The samples were heated at 560-860°C for 1 to 48h in air. Monophasic Bi-2212 samples was obtained for x=0.2 to 0.6 by heating above 730°C, which was approximately 100°C lower than that of the sample with x=0.A new compound containing Li element was formed in the temperature range between 700 and 720°C, which remarkably promoted the formation of the Bi-2212 phase. The lattice parameter c of the Bi-2212 phase increase with increasing Li content. The temperature dependence of magnetic susceptibility showed that Tc rose up to 90K for the sample with x=0.4 heated at 750°C for 12h.
Journal
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- Journal of the Japan Society of Powder and Powder Metallurgy
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Journal of the Japan Society of Powder and Powder Metallurgy 43 (2), 178-182, 1996
Japan Society of Powder and Powder Metallurgy
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Details 詳細情報について
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- CRID
- 1390282681283750912
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- NII Article ID
- 10002011276
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- NII Book ID
- AN00222724
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- ISSN
- 18809014
- 05328799
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- NDL BIB ID
- 3926714
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- Text Lang
- ja
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- Data Source
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- JaLC
- NDL
- Crossref
- CiNii Articles
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- Abstract License Flag
- Disallowed