プリカーサー法により合成されたセラミックスの結晶化

• 西村 論一

  室蘭工業大学工学部材料物性工学科

• 佐々木 眞

  室蘭工業大学工学部材料物性工学科

• 向井田 健一

  室蘭工業大学工学部材料物性工学科

書誌事項

タイトル別名

• Crystallization of Ceramics Derived from Organic Precursors.
• プリカーサーホウ ニ ヨリ ゴウセイサレタ セラミックス ノ ケッショウカ

抄録

Boron-containing Si-C-N-H polymers were fabricated. Amorphous ceramics were derived from the poly(silazane) and other organic polymer precursors. The precursor routes in this paper showed high ceramic yields in the range of 60 to 80%. Crystallization behavior of the boron-containing Si-C-N ceramics was investigated. The main crystalline phase was β-SiC. Crystalline size of the β-SiC decreased with increasing boron contents in the ceramics. And the X-ray intensity of the β-SiC also decreased with them. Heat treatment at 2373K in N₂ atmosphere introduced both β-SiC and free silicon, in the boron free Si-C-N ceramics and 1.6wt% boron-containing Si-C-N ceramics. 5.5wt% boron-containing Si-C-N ceramics showed crystalline phase of β-SiC and Si₃N₄. Boron may act as an inhibitant of both crystallization and decomposition of silicon nitride at high temperatures.

収録刊行物

• 粉体および粉末冶金

  粉体および粉末冶金 43 (3), 327-330, 1996

  一般社団法人 粉体粉末冶金協会

キーワード

• precursor
• ceramics
• crystallization
• β-SiC
• boron additive effect

詳細情報

• CRID: 1390001206309075840
• NII論文ID: 10002011630
• NII書誌ID: AN00222724
• DOI: 10.2497/jjspm.43.327
• ISSN: 18809014
• ISSN: 05328799
• NDL書誌ID: 3936699
• Web Site: https://ndlsearch.ndl.go.jp/books/R000000004-I3936699
• 本文言語コード: ja
• データソース種別:
  • JaLC
  • NDL
  • Crossref
  • CiNii Articles
• 抄録ライセンスフラグ: 使用不可