Structure Change of Graphite by Ball-Milling.

• Tanaka Takeo

  Dept. Mech. Eng., Fac. Eng., Osaka Sangyo University

• Yoshikawa Hiromi

  Fac. of Junior College of Automotive Industry, Osaka Sangyo University

• Kaneyoshi Takahiro

  Hyogo Prefectural Institute of Industrial Research

• Motoyama Muneyuki

  Hyogo Prefectural Institute of Industrial Research

• Ishihara Keiichi N.

  Dept. of Energy Science and Engineering, Kyoto University

• Shingu Paul Hideo

  Dept. of Energy Science and Engineering, Kyoto University

Bibliographic Information

Other Title

• アモルファス‐ナノ・グラニュラー機能材料　ＩＩ　ミリングによる黒鉛の構造変化
• ミリング ニヨル コクエン ノ コウゾウ ヘンカ

Abstract

Ball-milling of graphite powder was performed by the use of a stainless steel ball-mill and an agate ball-mill. The crystal structure of the ground graphite was studied by transmission electron microscopy and X-ray diffractometry. A spectrometric approach to the change of structure during the milling process was also carried out by the carbon Kα X-ray-emission band spectroscopy (XES). The carbon Kα XES spectra were compared with those of carbon materials such as ball-milled diamond powder, i-diamond film and amorphous carbon powder. In the case of the stainless steel ball-milling, microcrystalline and/or onion-like structure were formed. The XES spectrum suggested that sp³ hybrid orbital was formed after 2000 h of milling. While, in the case of an agate ball-milling, it was suggested that the 2p orbital became narrow as a result of further finely-ground pulverization of graphite crystallite after 1750 h of milling.

Journal

• Journal of the Japan Society of Powder and Powder Metallurgy

  Journal of the Japan Society of Powder and Powder Metallurgy 43 (6), 742-747, 1996

  Japan Society of Powder and Powder Metallurgy

Keywords

• graphite
• diamond
• mechanical grinding
• ball-milling
• structure change
• carbon Kα X-ray-emission band spectrum

Details

• CRID: 1390282681285260928
• NII Article ID: 10002012394
• NII Book ID: AN00222724
• DOI: 10.2497/jjspm.43.742
• ISSN: 18809014
• ISSN: 05328799
• NDL BIB ID: 3976293
• Web Site: https://ndlsearch.ndl.go.jp/books/R000000004-I3976293
• Text Lang: ja
• Data Source:
  • JaLC
  • NDL
  • Crossref
  • CiNii Articles
• Abstract License Flag: Disallowed