特集―分子性結晶ダイナミックス　結晶相不斉反応

• 関根 あき子

  東京工業大学理学部化学科

書誌事項

タイトル別名

• Special Issue-Dynamics of Molecular Crystals. Asymmetric Reaction in Crystalline-State.
• ケッショウソウ フセイ ハンノウ

抄録

The generation of asymmetry in a chiral crystal environment is very interesting in view point of the origin of life as well as organic syntheses. Two subjects are discussed; one is the asymmetric photoisomerization in chiral crystalline field and the other is a racemic-to-chiral transformation in a racemic crystal on exposure to visible light. Since the reactions proceed with retention of the single crystal form, the processes can be easily observed by X-ray analysis and the mechanism is explained on the basis of the reaction cavity which represents the void space around the reactive group in the crystal structure.

収録刊行物

• 日本結晶学会誌

  日本結晶学会誌 37 (1), 54-61, 1995

  日本結晶学会

詳細情報

• CRID: 1390001204087707008
• NII論文ID: 10002023980
• NII書誌ID: AN00188364
• DOI: 10.5940/jcrsj.37.54
• ISSN: 18845576
• ISSN: 03694585
• NDL書誌ID: 3595188
• Web Site: https://ndlsearch.ndl.go.jp/books/R000000004-I3595188
• 本文言語コード: ja
• データソース種別:
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• 抄録ライセンスフラグ: 使用不可