コバルト(III)錯体のニトロ-ニトリト結合異性化反応 Nitro-Nitrito Photochemical Isomerization of Cobalt (III)
Nitrite ion is a well-known ligand which shows linkage isomerism. The photo-isomerization in the solid state is governed by at least two factors: (a) electronic effect by coexisting ligands, and (b) reaction cavity of the nitro group. Recent X-ray study has revealed that the nitro-nitrito photo isomerization in a crystal is severely governed by intermolecular steric restrictions.
日本結晶学会誌 37(1), 62-68, 1995-02-28
The Crystallographic Society of Japan