Reaction System Involving Amplification of Chiral Selectivity by Secondary Nucleation.

• ASAKURA Kouichi

  Dept. of Applied Chemistry, Faculty of Science and Technology, Keio Univ

• OSANAI Shuichi

  Dept. of Applied Chemistry, Faculty of Science and Technology, Keio Univ

Bibliographic Information

Other Title

• 二次核生成によりキラル選択性が増幅される反応系
• 2ジ カク セイセイ ニ ヨリ キラル センタクセイ ガ ゾウフクサレル ハン

Abstract

Chiral autocatalysis is the system in which each enantiomer acts as a catalyst for its own production and an anticatalyst for the production of the other enantiomer. Predominant production of one enantiomer would occur if the reaction system involved chiral autocatalysis, since a slight difference between each enantiomer, which arises in the early stage of the reaction by statistical fluctuation could be augmented as the reaction proceeds. Some enantiomeric predominant products could be experimentally obtained by chirally autocatalytic secondary nucleation.

Journal

• Nihon Kessho Gakkaishi

  Nihon Kessho Gakkaishi 38 (3), 229-234, 1996

  The Crystallographic Society of Japan

Details

• CRID: 1390001204085902336
• NII Article ID: 10002025177
• NII Book ID: AN00188364
• DOI: 10.5940/jcrsj.38.229
• ISSN: 18845576
• ISSN: 03694585
• NDL BIB ID: 3984493
• Web Site: https://ndlsearch.ndl.go.jp/books/R000000004-I3984493
• Text Lang: en
• Data Source:
  • JaLC
  • NDL
  • Crossref
  • CiNii Articles
• Abstract License Flag: Disallowed