Selective Synthesis of Wax from Syngas by Supercritical Phase Process: Mass Transfer Effect of Co-Fed Olefin.

DOI Web Site Web Site 被引用文献3件 参考文献16件
  • Fan Li
    Department of Applied Chemistry, School of Engineering, The University of Tokyo
  • Yan Shirun
    Department of Applied Chemistry, School of Engineering, The University of Tokyo
  • Fujimoto Kaoru
    Department of Applied Chemistry, School of Engineering, The University of Tokyo
  • Yoshii Kiyotaka
    Ube R&D Lab., UBE Industries, Ltd.

書誌事項

タイトル別名
  • Selective Synthesis of Wax from Syngas

この論文をさがす

抄録

Addition of a small amount of middle olefins into a supercritical-phase Fischer-Tropsch reaction medium significantly promoted the carbon-chain growth and greatly enhanced the selectivity of waxy products, with increased CO conversion while successfully suppressing methane and CO2 selectivity. Hydrocarbon products exhibited anti-ASF distribution. The influences of reaction conditions and catalyst pore size, were studied for the supercritical-phase FT reaction where middle olefin was co-fed. This phenomenon was not observed in the gas-phase reaction and liquid-phase reaction conducted in a trickle bed. But liquid-phase reaction conducted in batch type reactor exhibited the same olefin addition effect. The reaction performances mentioned above were analyzed from the viewpoint of mass transfer efficiency of the added olefin in various reaction mediums.

収録刊行物

被引用文献 (3)*注記

もっと見る

参考文献 (16)*注記

もっと見る

キーワード

詳細情報 詳細情報について

問題の指摘

ページトップへ