Sorptive Removal of Cesium-137 and Strontium-90 from Water by Unconventional Sorbents. II. Usage of Coal Fly Ash

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著者

    • APAK Resat
    • Department of Chemistry, Faculty of Engineering, Istanbul University
    • ATUN Gulten
    • Department of Chemistry, Faculty of Engineering, Istanbul University
    • GUCLU Kubilay
    • Department of Chemistry, Faculty of Engineering, Istanbul University
    • TUTEM Esma
    • Department of Chemistry, Faculty of Engineering, Istanbul University

抄録

It has been shown that coal fly ash is a good adsorbent for both radionuclides of <SUP>137</SUP>Cs and <SUP>90</SUP>Sr. Radiocesium adsorption is maximal around the neutral region whereas radiostrontium adsorption increases with pH, especially above pH 8. Cesium retention sharply drops with ionic strength while strontium adsorption increases sharply and steadily at low and moderate concentrations of the inert electrolyte, respectively. The suggested mechanisms of radionuclide retention by fly ash is specific adsorption of Cs<SUP>+</SUP> and irreversible ion-exchange uptake of Sr<SUP>2+</SUP>. The isotherm of adsorption is a Langmuir approximation of the B.E.T. multi-layered sorption. Acid pretreatment of fly ash, though not increasing radionuclide sorption capacity, may be useful in preventing the leach-out of other contaminants from the sorbent into water during the adsorption process.

収録刊行物

  • Journal of nuclear science and technology  

    Journal of nuclear science and technology 33(5), p.396-402, 1996-05-25 

    Atomic Energy Society of Japan

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各種コード

  • NII論文ID(NAID)
    10002074741
  • NII書誌ID(NCID)
    AA00703720
  • 本文言語コード
    ENG
  • 資料種別
    ART
  • ISSN
    00223131
  • データ提供元
    CJP書誌  J-STAGE 
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