塩酸/硫酸混合溶液中におけるアルミニウムの交流エッチング AC Etching Characteristics of Aluminum in Hydrochloric/sulfuric Acid Solution
The large specific surface area on a low voltage-use aluminum electrolytic capacitor electrode was produced by alternating-current etching in a chlorine solution. The effect of sulfuric acid added to the 3.6% hydrochloric acid solution etchant on etch morphology was examined by Auger spectroscopy, electron microscopy, and galvanovoltammetry. Electrostatic capacitance, pit size, and amount of aluminum hydroxide formed during etching at 1∼50Hz in 3.6%HCl/<i>n</i>%H<sub>2</sub>SO<sub>4</sub>(<i>n</i>=0∼1) solution at 333K were determined. A deeper etched porous layer was produced in a 3.6%HCl/0.25%H<sub>2</sub>SO<sub>4</sub> solution than in a 3.6%HCl solution, with general dissolution prevented and surface film formation facilitated by the additive. The atomic ratio O/Al as calculated from the O (507eV) and Al-O (55eV) peaks of the surface film developed in a 3.6%HCl/0.25%H<sub>2</sub>SO<sub>4</sub> solution is 1.8∼2.0 higher than 1.5 for the etched film in a 3.6%HCl solution.
- 表面技術 = The Journal of the Surface Finishing Society of Japan
表面技術 = The Journal of the Surface Finishing Society of Japan 49(6), 643-648, 1998-06-01
The Surface Finishing Society of Japan