Vapor-liquid equilibria of methyl ethanoate with n-butyl and iso-butyl alcohol at 74.66 and 127.99kPa.

  • Susial Pedro
    Laboratorio de Termodinámica y Fisicoquimica, Escuela Superior de Ingenieros Industriales, Universidad de Lus Palmas de Gran Canaria
  • Ortega Juan
    Laboratorio de Termodinámica y Fisicoquimica, Escuela Superior de Ingenieros Industriales, Universidad de Lus Palmas de Gran Canaria

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Abstract

T-x-y data for binary systems containing methyl ethanoate + n-butyl alcohol and methyl ethanoate + iso-butyl alcohol were measured at 74.66 and 127.99 kPa using a dynamic method. No azeotrope was found and the mixtures studied exhibited positive deviations from ideality. All data, p-T-x-y were found to be thermodynamically consistent and application of the group contribution models ASOG and UNIFAC gave good predictions.

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