Transition Moment of the A2Δ-X2Π System of SiH Studied by Laser Induced Fluorescence Spectroscopy in Supersonic Free Expansions (レ-ザ-および放射光の半導体プロセス分野への応用特集号) Transition Moment of the A^2Δ-X^2Π System of SiH Studied by Laser Induced Fluorescence Spectroscopy in Supersonic Free Expansions

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Laser induced fluorescence (LIF) excitation spectra of the <I>A</I><SUP>2</SUP>Δ-<I>X</I><SUP>2</SUP>II transition of SiHhave been measured insupersonic free expansions. We observed the eight vibronic bands, 0-0, 1-0, 0-1, 1-1, 2-1, 1-2, 2-2, and 2-3, thethree Δ<I>v</I>=-1 bands of which were observed for the first time. The Δ<I>v</I>=0 sequencedominates the spectra, because of favorable Franck-Condon (F-C) factors. On the other hand, the intensities ofthe Δ<I>v</I>=- 1transitions are much weaker than those of the Δ<I>v</I>=+1 transitions in spite of theconsiderable intensity of Δ<I>v</I>=-1expected from the calculated F-C factors. This behavior is interpreted in terms of the transition momenthaving the strong dependence on internuclear distance.

収録刊行物

  • レーザー研究

    レーザー研究 26(6), 468-472, 1998-06

    The Laser Society of Japan

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各種コード

  • NII論文ID(NAID)
    10002249654
  • NII書誌ID(NCID)
    AN00255326
  • 本文言語コード
    ENG
  • 資料種別
    ART
  • ISSN
    03870200
  • NDL 記事登録ID
    4511852
  • NDL 雑誌分類
    ZN33(科学技術--電気工学・電気機械工業--電子工学・電気通信)
  • NDL 請求記号
    Z16-1040
  • データ提供元
    CJP書誌  NDL  J-STAGE 
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