Electrodeposition of CuInSe2 in Acidic Solution and its Photoelectrochemical Response.

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  • 酸性水溶液からのCuInSe2の電析と光電気化学応答
  • サンセイ スイヨウエキ カラ ノ CuInSe2 ノ デンセキ ト ヒカリ デ

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Abstract

CuInSe2 was electrodeposited on a Ti substrate from an acidic solution with Cu, In, and Se ions. Cu-Se codeposition started below 0.1V and CuInSe2 was detected below -0.5V. H2 gas evolved under -0.8V. The morphology of CuInSe2 showed a dendritic structure due to the effect of Se0 to Se2- reduction. Deposits formed at -0.5V were p-type semiconductor because cathode currents for deposits in sulphic solutions increased by light irradiation, and the photocurrent for deposits after heat treatment increased greatly.

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