A Mechanism of Improved Paint Adhesion by Ni Surface Conditioning Prior to Dry-in-place Chromate Treatment.

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  • Ni表面調整処理によるカラー鋼板の塗膜密着性向上メカニズム
  • Ni ヒョウメン チョウセイ ショリ ニヨル カラー コウハン ノ トマク ミ

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Abstract

In this study, we investigated a mechanism for improving paint adhesion by using Ni surface conditioning prior to dry-in-place chromate treatment, which is usually applied to hot dip Zn-coated steel sheets as a paint base.<br>The results showed that the scattered deposits of Ni on the Zn surface formed micro cells with the Zn as the anode and the Ni as the cathode.<br>Through these micro cells, insoluble chromate film (Cr(III)) deposited on the Ni through an electrochemical reaction of reducing the Cr(VI) in the dry-in place chromate solution.<br>This mechanism of generating chromate film should contribute greatly to improved paint adhesion.

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