Pd添加による珪化鉄のε+α→β変態と焼結の促進 Accelerations of ε+α→βTransformation and Sintering of Iron Silicide by Addition of Pd

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FeSi<SUB>2</SUB>(β phase) semiconducting iron silicide, which is expected to be widely used as a thermoelectric material in high temperature environment, is formed below 1259K by the peritectoid reaction of FeSi(ε) and Fe<SUB>2</SUB>Si<SUB>5</SUB>(α) two metallic phases. Because the transformation of ε+α→β caused by this peritectoid reaction occurs considerably slowly, the iron silicide material which is produced by sintering of the powder at temperatures above 1259K has to be isothermally heat-treated for at least 180ks at about 1120K after the sintering so that the transformation occurs completely.<BR>We have found that the transformation was drastically accelerated by the addition of a small amount of Pd in the same way as Cu; the isothermal heat-treatment time necessary for the completion of the transformation was reduced to about 1/60. The sintering time needed for the almost full densification of the powder by pressure DCL sintering (DCL; direct current loading) was also reduced. A hypothesis for the mechanisms was proposed.

収録刊行物

  • 粉体および粉末冶金  

    粉体および粉末冶金 43(12), 1473-1478, 1996-12-15 

    Japan Society of Powder and Powder Metallurgy

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各種コード

  • NII論文ID(NAID)
    10002261282
  • NII書誌ID(NCID)
    AN00222724
  • 本文言語コード
    JPN
  • 資料種別
    ART
  • ISSN
    05328799
  • NDL 記事登録ID
    4118686
  • NDL 雑誌分類
    ZP41(科学技術--金属工学・鉱山工学)
  • NDL 請求記号
    Z17-274
  • データ提供元
    CJP書誌  CJP引用  NDL  J-STAGE 
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