Lithium Insertion Behaviour of (H3N(CH2)3NH3)[V4O10] (特集 電池・イオン導電性材料) Lithium Insertion Behaviour of (H_3N(CH_2)_3NH_3)[V_4O_<10>]

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Electrochemical behaviour of (NH<SUB>3</SUB>(CH<SUB>2</SUB>)<SUB>3</SUB>NH<SUB>3</SUB>)<SUB>y</SUB>[V<SUB>4</SUB>O<SUB>10</SUB>] (1) was investigated as lithium insertion host. By thermal treatment above 250°C it was possible to remove the organic constituent in the interlayer from the compound (1) at 250°C, and the original layer structure was maintained up to about y>0.75 in (NH<SUB>3</SUB>(CH<SUB>2</SUB>)<SUB>3</SUB>NH<SUB>3</SUB>)<SUB>y</SUB>[V<SUB>4</SUB>O<SUB>10</SUB>]. Lithium ions were inserted electrochemically in the compound (1), and amount of lithium inserted in the interlayer increased as y decreased. This increase was caused by increase in the available sites for lithium ions and largely by enhancement of diffusion rate in the interlayer.

収録刊行物

  • 粉体および粉末冶金  

    粉体および粉末冶金 46(3), 305-311, 1999-03-15 

    Japan Society of Powder and Powder Metallurgy

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各種コード

  • NII論文ID(NAID)
    10002262123
  • NII書誌ID(NCID)
    AN00222724
  • 本文言語コード
    ENG
  • 資料種別
    ART
  • ISSN
    05328799
  • NDL 記事登録ID
    4690260
  • NDL 雑誌分類
    ZP41(科学技術--金属工学・鉱山工学)
  • NDL 請求記号
    Z17-274
  • データ提供元
    CJP書誌  NDL  J-STAGE 
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