合成糖脂質―加水分解酵素モデルとして

• 大勝 靖一

  工学院大学工学部

書誌事項

タイトル別名

• Synthetic Glycolipids-As Hydrolase Models.
• ゴウセイ トウ シシツ カスイ ブンカイ コウソ モデル ト シテ

抄録

Synthetic Glycolipids, which contain cyclic or acyclic suger moieties connected, in some, cases, with amino acid (s), have hydrolyzing abilities as hydrolase models. Characteristics of these models are made clear in comparison with those of other models, mainly histidine derivatives substituted with higher alkyl group (s), proposed so far. That is, synthetic glycolipids are distinguished by hydrolyzing activities that they do not need coexistence of amphiphilic substance (s) which are indispensable for other hydrolase models, that they can hydrolyze not only ester bonds, but amide and glycoside bonds which are too strong to be hydrolyzed by other models, and that, in addition to recognition of D, L-configuration of amino acides, they can recognize kinds of amino acids as well as α, β-glycoside bonds. The active site of glycolipids on hydrolyses and the effect of reaction fields on hydrolyzing activities of glycolipids are also discussed.

収録刊行物

• 日本油化学会誌

  日本油化学会誌 45 (1), 3-12, 1996

  公益社団法人 日本油化学会

キーワード

• synthetic glycolipid
• hydrolase model
• hydrolysis
• amino acid glycoside bond

詳細情報

• CRID: 1390001204091287296
• NII論文ID: 10002268280
• NII書誌ID: AN10512582
• DOI: 10.5650/jos1996.45.3
• ISSN: 18841996
• ISSN: 13418327
• NDL書誌ID: 3954762
• Web Site: https://ndlsearch.ndl.go.jp/books/R000000004-I3954762
• Web Site: https://www.jstage.jst.go.jp/article/jos1996/45/1/45_1_3/_pdf
• 本文言語コード: ja
• データソース種別:
  • JaLC
  • NDL
  • Crossref
  • CiNii Articles
• 抄録ライセンスフラグ: 使用不可