Structures and Antioxidative Activity of retro Carotenoids from the Berries of the Japanese Yew, Taxus cuspidata.

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  • 日本産イチイ(Taxus cuspidata)果実のレトロタイプカロテノイドの構造と酸化作用
  • ニホンサン イチイ Taxus cuspidata カジツ ノ レトロタイプカ

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Abstract

The structures and antioxidative activity of retro carotenoids from the berries of the Japanese yew, Taxus cuspidata were studied. Three retro carotenoids, rhodoxanthin (1), eschscholtzxanthone (2) and eschscholtzxanthin (3) were identified by spectroscopy. The stereo-structure of (2) was fully determined based on 1H-NMR and CD spectral data. These retro carotenoids showed stronger antioxidative activity for lipid peroxidation induced by free radical and singlet oxygen than that of β-carotene.

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