ヒル, <I>Hirudo nipponia</I>におけるGalα1-6 Gal及びGalβ1-6 Gal構造を有するスフィンゴ糖脂質

書誌事項

タイトル別名
  • Glycosphingolipids with Gal.ALPHA.1-6Gal and Gal.BETA.1-6Gal Sequences in the Leech, Hirudo nipponia.
  • Glycosphingolipids with Galα1-6Gal and Galβ1-6Gal Sequences in the Leech,Hirudo nipponia
  • Glycosphingolipids with Galアルファ1-6Gal a

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抄録

Glycosphingolipids containing two gala-6 core series were shown to be present in the leech, Hirudo nipponia. Their structures were determined as Gal β1-1Cer, Galα1-6Gal β1-1Cer, Galα1-6Galα1-6Galβ1-Cer and Galα1-6Galα1-6Galα1-6Galβ1-Cer as neutral glycolipids and cholinephosphate→6Galβ1-1Cer and cholinephosphate→6Galβ1-6Galβ1-1Cer as amphoteric glycolipids, based on the results of compositional and methylation analyses and exogalactosidase treatments. Ceramides mainly contained C16 : 0, C18 : 0, C22 : 0 and C24 : 0 fatty acids and dihydroxy- (C18 : 1, C19 : 1 and C22 : 3) and trihydroxy- (C18 : 0 and C19 : 0) sphingoids. The authors tentatively designated the disaccharide structure, Galα1-6Gal, as the “isoneogala-series”, which may represent a new type of glycosphingolipid core series.

収録刊行物

  • 日本油化学会誌

    日本油化学会誌 45 (8), 731-740, 1996

    公益社団法人 日本油化学会

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