両親媒性高分子の自己組織化と溶液物性

書誌事項

タイトル別名
  • Self-Organization of Amphiphilic Polymers and Their Solution Properties
  • リョウシンバイセイ コウブンシ ノ ジコ ソシキカ ト ヨウエキ ブッセイ

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抄録

This review focuses on the self-organization of novel amphiphilic polymers prepared by relatively simple synthetic techniques including free-radically initiated random copolymerization of hydrophilic and hydrophobic monomers and chemical modification of water-soluble polymers with functional hydrophobic molecules. These polymers exhibit various types of self-organization in aqueous solution due to intra- and/or interpolymer hydrophobic associations depending on the chemical structure of the polymers. Structural factors that affect the self-organization behavior include the type and content of hydrophobes contained in the polymers, distribution of the hydrophobic and hydrophilic units within a polymer chain, and spacer bond between the hydrophobe and the polymer chain. Various types of micelles are formed as a result of various modes of the self-organization. The relationship between the polymer structure and the micellar structure is discussed.

収録刊行物

  • 日本油化学会誌

    日本油化学会誌 45 (10), 951-959,1203, 1996

    公益社団法人 日本油化学会

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