合成ゼオライト触媒による (+) -2-ピネン, (-) -2 (10) -ピネンおよび (+) -1-<I>p</I>-メンテンのアシル化注

• 野村 正人

  近畿大学工学部工業化学科

• 久冨 智

  近畿大学工学部工業化学科

• 濱田 敏正

  近畿大学工学部工業化学科

• 藤原 義人

  近畿大学工学部工業化学科

書誌事項

タイトル別名

• Acylation of (+) -2-Pinene, (-) -2 (10) -Pinene and (+) -1-<I>p</I>-Menthene by Synthetic Zeolite Catalysts
• ゴウセイ ゼオライト ショクバイ ニヨル+2 ピネンー 2 10 ピネン オヨ

抄録

Examination was made of acylation reactions of (+) -2-pinene (1), (-) -2 (10) -pinene (2) and (+) -1-p-menthene (3) with acid anhydrides (acetic anhydride and propionic anhydride) in the presence of synthetic zeolites and the following results were obtained. With US-Y type zeolites, (4) (13) were obtained from (1) (3) as the main products, respectively and evaluated on the basis of odor ; (9) emitted odors that would qualify them as flavor agents. The antimicrobial activity of acylated compounds (4) (13) toward Bacillus subtilis, Staphylococcus aureus, Escherichia coli, Aspergillus niger and Penicillium citrinum was also examined and it was found that compound (7) (at 100 μg/mL) derived from (1) and (2), completely inhibited the growth of B. subtilis.

収録刊行物

• 日本油化学会誌

  日本油化学会誌 46 (5), 583-587,600, 1997

  公益社団法人 日本油化学会

キーワード

• acylation
• monoterpenes
• acid anhydrides
• flavor materials
• synthetic zeolites

詳細情報

• CRID: 1390001204093469824
• NII論文ID: 10002272681
• NII書誌ID: AN10512582
• DOI: 10.5650/jos1996.46.583
• ISSN: 18841996
• ISSN: 13418327
• NDL書誌ID: 4216996
• Web Site: https://ndlsearch.ndl.go.jp/books/R000000004-I4216996
• Web Site: https://www.jstage.jst.go.jp/article/jos1996/46/5/46_5_583/_pdf
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