書誌事項
- タイトル別名
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- Synthesis and Application of γ-Zirconium Phosphates Modified with Chiral Amines
- コウガク カッセイ アミン タンジガンマ リンサン ジルコニウム ノ ゴウセイ
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The intercalation of organic phosphate esters and chiral amines into layered γ-zirconium phosphate, Zr (HPO4)2·2H2O (abbreviated ZrP), was examined by powder X-ray diffraction, elemental analysis and IR spectroscopy. The results indicated basal spacings of ZrP intercalated with organic phosphate esters to enlarge in proportion to alkyl chain length. When chiral amines were further intercalated into ZrP derivatives, the basal spacings became slightly longer. The catalytic activity of the modified ZrP derivatives was investigated by adding thiol to enone. Enantiomeric excess was found to depend on the chiral amine employed and the alkyl chain length of organic phosphate.
収録刊行物
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- 日本油化学会誌
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日本油化学会誌 46 (8), 915-919,938, 1997
公益社団法人 日本油化学会
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詳細情報 詳細情報について
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- CRID
- 1390001204091403264
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- NII論文ID
- 10002273176
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- NII書誌ID
- AN10512582
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- ISSN
- 18841996
- 13418327
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- NDL書誌ID
- 4285217
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- データソース種別
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- JaLC
- NDL
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- CiNii Articles
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- 抄録ライセンスフラグ
- 使用不可