Methanol Synthesis from Carbon Dioxide and Hydrogen via Formic Ester.
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- Sakaiya Yoshitada
- Department of Applied Chemistry, School of Engineering, The University of Tokyo
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- Fan Li
- Department of Applied Chemistry, School of Engineering, The University of Tokyo
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- Fujimoto Kaoru
- Department of Applied Chemistry, School of Engineering, The University of Tokyo
Bibliographic Information
- Other Title
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- Methanol Synthesis from Carbon Dioxide
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Abstract
A new route of methanol synthesis, at 473K and 30bar, from carbon dioxide and hydrogen through formic ester was reported, by using active carbon supported palladium catalyst and coexisting weak base. This one-pot reaction consisted of 3 steps: (1) formic acid synthesis from CO2 and H2, (2) esterification of formic acid by ethanol to ethyl formate, (3) hydrogenolysis of ethyl formate to methanol and ethanol, the rate-determining step. Longer reaction time favored methanol synthesis and high CO2 conversion.
Journal
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- Journal of The Japan Petroleum Institute
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Journal of The Japan Petroleum Institute 41 (5), 354-357, 1998
The Japan Petroleum Institute
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Details 詳細情報について
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- CRID
- 1390282681273452288
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- NII Article ID
- 10002286409
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- NII Book ID
- AN00130954
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- NDL BIB ID
- 4545986
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- ISSN
- 05824664
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- Text Lang
- en
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- Data Source
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- JaLC
- NDL
- Crossref
- CiNii Articles
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- Abstract License Flag
- Disallowed