Homogeneous Solvent Extraction/Solid-Liquid Separation Method of Some Metal-Chelate Compounds Using Caffeine

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Polarographic reduction behaviors of <I>fac</I>-[Cr(AA)<SUB>3</SUB>] complexes, where AA is an L-α-amino acidato ligand, have been studied in Me<SUB>2</SUB>SO. These complexes showed two reduction waves at mercury electrode and the first corresponded to Cr(III) → Cr(II). This reduction potential was found to be more positive for the (+)<SUB>546</SUB>-isomer than for the corresponding (−)<SUB>546</SUB>-isomer in the presence of Et<SUB>4</SUB>N<SUP>+</SUP>.

収録刊行物

  • Analytical sciences : the international journal of the Japan Society for Analytical Chemistry  

    Analytical sciences : the international journal of the Japan Society for Analytical Chemistry 12(5), 789-792, 1996-10-10 

    The Chemical Society of Japan

参考文献:  10件

各種コード

  • NII論文ID(NAID)
    10002409695
  • NII書誌ID(NCID)
    AA10500785
  • 本文言語コード
    ENG
  • 資料種別
    NOT
  • ISSN
    09106340
  • データ提供元
    CJP書誌  J-STAGE 
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