Stereoselectivity in the Polarographic Reduction of Chromium(III) Complexes with L-α-Amino Acids
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- Hisaya Oki
- Department of Chemistry, Faculty of Education, Fukui University
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- Hideya Gessoh
- Department of Chemistry, Faculty of Education, Fukui University
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- Ryuji Nakata
- Department of Chemistry, Faculty of Education, Fukui University
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<jats:title>Abstract</jats:title> <jats:p>Polarographic reduction behaviors of fac-[Cr(AA)3] complexes, where AA is an L-α-amino acidato ligand, have been studied in Me2SO. These complexes showed two reduction waves at mercury electrode and the first corresponded to Cr(III) → Cr(II). This reduction potential was found to be more positive for the (+)546-isomer than for the corresponding (−)546-isomer in the presence of Et4N+.</jats:p>
収録刊行物
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- Chemistry Letters
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Chemistry Letters 20 (5), 789-792, 1991-05-01
Oxford University Press (OUP)
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詳細情報 詳細情報について
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- CRID
- 1360846644038655744
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- NII論文ID
- 10002409695
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- NII書誌ID
- AA10500785
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- ISSN
- 13480715
- 03667022
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