Sodium Selective Ion-Exchange Properties of Zirconium Phosphate, HZr2(PO4)3, and Its Application for the Removal of Sodium Ions.

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タイトル別名
  • Sodium Selective Ion-Exchange Propertie

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抄録

Zirconium phosphate, HZr2(PO4)3 (NZP), in a powder form was synthesized from zirconium chloride oxide and sodium dihydrogenphosphate, and its ion exchange adsorption properties to alkali metal ions were studied. The ion-exchange adsorption partition coefficients of NZP to alkali metal ions at pH=3.4 were found to be 3.2×103(Li+), 4.5×105(Na+), 2.6 (K+), 12 (Rb+), and 380 (Cs+) cm3 g-1. The results indicate that NZP has a high adsorbability to sodium ions. Mixed granules of NZP and silica sol (NZP-P) were then prepared and applied for the selective removal of sodium ions by a column adsorption method.

収録刊行物

  • Analytical Sciences

    Analytical Sciences 12 (6), 935-940, 1996

    社団法人 日本分析化学会

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