Solvent Extraction of Transition Metal Ions by an in situ Extractant Formation Method. Diethyldithiocarbamate-Forming System.

  • FUJINAGA Kaoru
    Department of Material Sciences, Interdisciplinary Faculty of Science and Engineering, Shimane University
  • SEIKE Yasushi
    Department of Material Sciences, Interdisciplinary Faculty of Science and Engineering, Shimane University
  • OKUMURA Minoru
    Department of Material Sciences, Interdisciplinary Faculty of Science and Engineering, Shimane University

書誌事項

タイトル別名
  • Solvent Extraction of Transition Metal

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抄録

By mixing carbon disulfide and diethylamine in chloroform prior to use, diethyldithiocarbamic acid forms. Such metal ions as Cu2+, Co2+, Zn2+, Ni2+, Cd2+, Fe3+, and Mn2+ were quantitatively extracted from an aqueous sulfate medium as a diethyldithiocarbamate complex. The optimum extraction conditions, such as the pH, mixing ratio of reagents, and shaking time for equilibrium, were established.

収録刊行物

  • Analytical Sciences

    Analytical Sciences 13 (2), 225-230, 1997

    社団法人 日本分析化学会

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