A New Relationship on the Partition Equilibrium of Carboxylic Acids between 1-Octanol/Water and Benzene/Water Systems.
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- YAMADA Hiromichi
- Department of Applied Chemistry, Nagoya Institute of Technology
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- NAITO Tetsuyoshi
- Department of Applied Chemistry, Nagoya Institute of Technology
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- MIWA Kazuto
- Department of Applied Chemistry, Nagoya Institute of Technology
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- TACHI Noriyuki
- Department of Applied Chemistry, Nagoya Institute of Technology
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- WADA Hiroko
- Department of Applied Chemistry, Nagoya Institute of Technology
書誌事項
- タイトル別名
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- New Relationship on the Partition Equil
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The partition constants of a number of carboxylic acids were determined for the partition systems using 1-octanol and benzene as a solvent, and the dimerization constants of carboxylic acids in the benzene phase were also determined. A linear relationship between the partition constants (log KD, HA) of carboxylic acids and the molar volume of the respective carboxylic acids was found. A new good relationship on the partition equilibrium of carboxylic acids was found between the partition systems using 1-octanol and benzene, that is, a good linear relationship exists between the values of (log K2, HA+2log KD, HA) for benzene/water system and the values of log KD, HA for 1-octanol/water system, irrespective of the kinds of carboxylic acids.
収録刊行物
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- Analytical Sciences
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Analytical Sciences 13 (6), 897-902, 1997
社団法人 日本分析化学会
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詳細情報 詳細情報について
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- CRID
- 1390001204252156672
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- NII論文ID
- 130003528249
- 10002413241
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- NII書誌ID
- AA10500785
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- COI
- 1:CAS:528:DyaK2sXotVWmurs%3D
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- ISSN
- 13482246
- 09106340
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- NDL書誌ID
- 4357468
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- 本文言語コード
- en
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- データソース種別
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- JaLC
- NDL
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- 使用不可