Response Characteristics of Anion-Selective Polymeric Membrane Electrodes Based on Gallium(III),Indium(III)and Thallium(III)Porphyrins

• STEINLE Erich D.

  Department of Chemistry, The University of Michigan

• SCHALLER Ulrich

  Department of Chemistry, The University of Michigan

• MEYERHOFF Mark E.

  Department of Chemistry, The University of Michigan

書誌事項

タイトル別名

• Response Characteristics of Anion-Selective Polymer Membrane Electrodes Based on Gallium(III), Indium(III) and Thallium(III) Porphyrins.
• Response Characteristics of Anion-Selec

抄録

The potentiometric anion responses of ion-selective electrodes prepared with polymeric membranes doped with gallium(III), indium(III) and thallium(III) metalloporphyrins are examined. These group XIII metals, when inserted into either octaethyl- or tetraphenyl-porphyrin derivatives and subsequently incorporated into plasticized poly(vinyl chloride) membranes, serve as anion ionophores with selectivity patterns that deviate significantly from the classical Hofmeister series for anions. The gallium(III) porphyrin-based electrodes exhibit significantly enhanced response toward fluoride, whereas the indium(III) and thallium(III) porphyrins display some preference for chloride and also effectively discriminate less hydrated anions such as perchlorate and nitrate. All of the metalloporphyrins investigated are determined to function via a charged carrier response mechanism. This mechanism is elucidated by correlating the effect of adding lipophilic ionic sites, either cationic (quaternary ammonium) or anionic (tetraphenylborate) salts, to the observed anion selectivity and response patterns of the metalloporphyrin-based liquid /polymer membrane electrodes.

収録刊行物

• Analytical Sciences

  Analytical Sciences 14 (1), 79-84, 1998

  社団法人 日本分析化学会

キーワード

• Analytical Chemistry

詳細情報

• CRID: 1390282679230126464
• NII論文ID: 10002414150
• NII書誌ID: AA10500785
• DOI: 10.2116/analsci.14.79
• COI: 1:CAS:528:DyaK1cXhtV2qtL0%3D
• ISSN: 13482246
• ISSN: 09106340
• ISSN: http://id.crossref.org/issn/09106340
• NDL書誌ID: 4406426
• Web Site: https://ndlsearch.ndl.go.jp/books/R000000004-I4406426
• Web Site: https://link.springer.com/content/pdf/10.2116/analsci.14.79.pdf
• Web Site: https://link.springer.com/article/10.2116/analsci.14.79/fulltext.html
• Web Site: http://www.jstage.jst.go.jp/article/analsci/14/1/14_1_79/_pdf
• 本文言語コード: en
• データソース種別:
  • JaLC
  • NDL
  • Crossref
  • CiNii Articles
• 抄録ライセンスフラグ: 使用不可