Calculation of Concentration and Electrostatic Potential Profiles at Liquid-Membrane/Water and Liquid/Liquid Interfaces

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A method based on statistical thermodynamics has been used to describe concentration distributions of neutral and charged molecules in the vicinity of liquid-liquid or polymer membrane-liquid interfaces. The model is outlined and various applications are shown. One of these is a study of the transition region at the interface of two immiscible liquids. The results show that this transition is not sharp. The width of the interfacial region (where the concentration varies gradually) depends on the mutual solubility of the two liquids and on the size of the molecules. In another application the potential drop across the interfacial region has been calculated as a function of composition of the bulk phases. This type of calculation allowed the numerical simulation of the potentiometric behavior of a recently developed ion-selective electrode which employs negatively charged ion carrier.

収録刊行物

  • Analytical sciences : the international journal of the Japan Society for Analytical Chemistry

    Analytical sciences : the international journal of the Japan Society for Analytical Chemistry 14(1), 137-140, 1998-02-10

    社団法人 日本分析化学会

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各種コード

  • NII論文ID(NAID)
    10002414416
  • NII書誌ID(NCID)
    AA10500785
  • 本文言語コード
    ENG
  • 資料種別
    ART
  • ISSN
    09106340
  • NDL 記事登録ID
    4406435
  • NDL 雑誌分類
    ZP4(科学技術--化学・化学工業--分析化学)
  • NDL 請求記号
    Z54-F482
  • データ提供元
    CJP書誌  NDL  J-STAGE 
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