Naked-Eye Detectable Chiral Recognition Using a Chromogenic Receptor.

  • KUBO Yuji
    Department of Applied Chemistry, Faculty of Engineering, Saitama University
  • HIROTA Naohisa
    Department of Applied Chemistry, Faculty of Engineering, Saitama University
  • MAEDA Shi’nya
    Department of Applied Chemistry, Faculty of Engineering, Saitama University
  • TOKITA Sumio
    Department of Applied Chemistry, Faculty of Engineering, Saitama University

Bibliographic Information

Other Title
  • Naked-Eye Detectable Chiral Recognition

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Abstract

This article is concerned with our recent achievement in developing synthetic chromogenic receptors for optical active amines and amino acid derivatives. Pre-organized (S)-1,1′-bi-2-naphthyl- and bis(indophenol)-derived calix[4]crown 1a shows naked-eye detectable chiral recognition between those enantiomers. The spectroscopic properties are reported, as well as an estimation of the enantioselectivity using an HPLC equipped with a chiral packing column.

Journal

  • Analytical Sciences

    Analytical Sciences 14 (1), 183-189, 1998

    The Japan Society for Analytical Chemistry

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