Computational Aspects of Extraction Equilibrium and Distribution Potential of Electrolyte Distributed between Two Liquid Polar Phases.

• RAIS Jirí

  Nuclear Research Institute

Bibliographic Information

Other Title

• Computational Aspects of Extraction Equ

Abstract

It is proved that both “electrochemical” and “chemical” treatments of the equilibrium distribution of electrolytes between two polar solvents are correct, or in other words the use of electrochemical or chemical potentials is interchangeable. This is illustrated by calculation using a recursive iteration program for distribution of Sr²⁺ by dicarbollide anion in the presence of polyethyleneglycol. Several particular situations are described: the effect of common ion, limiting distribution coefficient and influence of protonized particles on distribution of cations.

Journal

• Analytical Sciences

  Analytical Sciences 14 (2), 293-297, 1998

  The Japan Society for Analytical Chemistry

Keywords

• Analytical Chemistry

Details

• CRID: 1390001204254649472
• NII Article ID: 130004439804
• NII Article ID: 10002415047
• NII Book ID: AA10500785
• DOI: 10.2116/analsci.14.293
• COI: 1:CAS:528:DyaK1cXislGmtr0%3D
• ISSN: 13482246
• ISSN: 09106340
• NDL BIB ID: 4450410
• Web Site: https://ndlsearch.ndl.go.jp/books/R000000004-I4450410
• Web Site: https://link.springer.com/content/pdf/10.2116/analsci.14.293.pdf
• Web Site: https://link.springer.com/article/10.2116/analsci.14.293/fulltext.html
• Web Site: http://www.jstage.jst.go.jp/article/analsci/14/2/14_2_293/_pdf
• Text Lang: en
• Data Source:
  • JaLC
  • NDL
  • Crossref
  • CiNii Articles
• Abstract License Flag: Disallowed