Extraction of Arsenic(III) with Macroporous Resin Impregnated with Bis(2-ethylhexyl)ammonium Bis(2-ethylhexyl)-dithiocarbamate.

• WAKUI Yoshito

  Tohoku National Industrial Research Institute

• NDIAYE Serigne A.

  Faculty of Sciences and Techniques, Universite Cheikh Anta DIOP

• MATSUNAGA Hideyuki

  Tohoku National Industrial Research Institute

• YOKOYAMA Toshirou

  Tohoku National Industrial Research Institute

• AKIBA Kenichi

  Institute for Advanced Materials and Processing, Tohoku University

書誌事項

タイトル別名

• Extraction of Arsenic 3 with Macroporou

抄録

The extraction of arsenic(III) was investigated by using macroporous resin impregnated with a newly synthesized hydrophobic extractant: bis(2-ethylhexyl)ammonium bis(2-ethylhexyl)dithiocarbamate (BBDC). In a preliminary experiment on liquid-liquid extraction, arsenic(III) was favorably extracted with BBDC in heptane from acidic to neutral solutions; the distribution ratios with 0.01 mol dm^-3 BBDC were larger than 10^2.5 at pH 0 - 6. The batchwise extraction of arsenic(III) with the impregnated resin was carried out. The distribution ratio was more than 10³ in an acidic region, and sharply decreased above pH 8. The collection of a trace amount of arsenic(III) was performed by using the column packed with the impregnated resin as a stationary phase. Then arsenic(III) retained on the column was quantitatively eluted out with an alkaline solution.

収録刊行物

• Analytical Sciences

  Analytical Sciences 14 (2), 299-303, 1998

  社団法人 日本分析化学会

キーワード

• Analytical Chemistry

詳細情報

• CRID: 1390001204254650496
• NII論文ID: 130004439805
• NII論文ID: 10002415065
• NII書誌ID: AA10500785
• DOI: 10.2116/analsci.14.299
• COI: 1:CAS:528:DyaK1cXislGmtro%3D
• ISSN: 13482246
• ISSN: 09106340
• ISSN: http://id.crossref.org/issn/09106340
• NDL書誌ID: 4450411
• Web Site: https://ndlsearch.ndl.go.jp/books/R000000004-I4450411
• Web Site: https://link.springer.com/content/pdf/10.2116/analsci.14.299.pdf
• Web Site: https://link.springer.com/article/10.2116/analsci.14.299/fulltext.html
• Web Site: http://www.jstage.jst.go.jp/article/analsci/14/2/14_2_299/_pdf
• 本文言語コード: en
• データソース種別:
  • JaLC
  • NDL
  • Crossref
  • CiNii Articles
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