Determination of Cadmium and Lead in Tap Water by Graphite-Furnace Atomic Absorption Spectrometry after Preconcentration on a Finely Divided Ion-Exchange Resin as the Pyrrolidinedithiocarbamate Complexes.

• ANEZAKI Katsunori

  Department of Materials Science and Technology, Faculty of Science and Technology, Hirosaki University

• CHEN Xueze

  Department of Materials Science and Technology, Faculty of Science and Technology, Hirosaki University

• OGASAWARA Tamotsu

  Department of Materials Science and Technology, Faculty of Science and Technology, Hirosaki University

• NUKATSUKA Isoshi

  Department of Materials Science and Technology, Faculty of Science and Technology, Hirosaki University

• OHZEKI Kunio

  Department of Materials Science and Technology, Faculty of Science and Technology, Hirosaki University

Bibliographic Information

Other Title

• Determination of Cadmium and Lead in Ta

Abstract

A rapid and simple preconcentration method based on the combined use of ammonium pyrrolidinedithiocarbamate (APDC) and a finely divided anion-exchange resin has been described for the determination of trace amounts of cadmium and lead by graphite-furnace atomic absorption spectrometry (GFAAS). Cadmium- and lead-APDC complexes were extracted simultaneously on the resin at pH 6. The resin particles holding the cadmium- and lead-APDC complexes were separated by filtration and dispersed in 1.0 ml of 0.1 mol l^-1 hydrochloric acid containing 100 μg of palladium(II). The resulting suspension was introduced directly into the graphite furnace by an automatic sampler. The detection limits of cadmium and lead in a 150-ml sample aliquot were 0.17 and 5.7 ng l^-1, respectively, based on three-times the standard deviation of blank values. The proposed method was applied to the determination of nanograms per liter levels of cadmium and lead in tap water.

Journal

• Analytical Sciences

  Analytical Sciences 14 (3), 523-527, 1998

  The Japan Society for Analytical Chemistry

Keywords

• Analytical Chemistry

Details

• CRID: 1390001204253665024
• NII Article ID: 130004439851
• NII Article ID: 10002415783
• NII Book ID: AA10500785
• DOI: 10.2116/analsci.14.523
• COI: 1:CAS:528:DyaK1cXjvFKktLY%3D
• ISSN: 13482246
• ISSN: 09106340
• NDL BIB ID: 4514234
• Web Site: https://ndlsearch.ndl.go.jp/books/R000000004-I4514234
• Web Site: https://link.springer.com/content/pdf/10.2116/analsci.14.523.pdf
• Web Site: https://link.springer.com/article/10.2116/analsci.14.523/fulltext.html
• Web Site: http://www.jstage.jst.go.jp/article/analsci/14/3/14_3_523/_pdf
• Text Lang: en
• Data Source:
  • JaLC
  • NDL
  • Crossref
  • CiNii Articles
• Abstract License Flag: Disallowed