Design and Preparation of Molecularly Imprinted Atrazine-Receptor Polymers: Investigation of Functional Monomers and Solvents.

DOI PDF Web Site Web Site Web Site ほか1件をすべて表示 一部だけ表示 被引用文献4件 参考文献17件
  • MATSUI Jun
    Laboratory of Synthetic Biochemistry, Faculty of Information Sciences, Hiroshima City University
  • KUBO Hiroyuki
    Laboratory of Synthetic Biochemistry, Faculty of Information Sciences, Hiroshima City University
  • TAKEUCHI Toshifumi
    Laboratory of Synthetic Biochemistry, Faculty of Information Sciences, Hiroshima City University

書誌事項

タイトル別名
  • Design and Preparation of Molecularly I

この論文をさがす

抄録

The preparation of atrazine-receptor polymers by molecular imprinting was explored, focusing upon the role of functional monomer and solvent used for the preparation. Three functional monomers and six different solvents were examined from the viewpoint of the efficiency for molecular imprinting. Polymers were prepared using methacrylic acid, a stronger acid 2-(trifluoromethyl)acrylic acid and a three-point hydrogen bond donor/acceptor, glutethimide derivative. Methacrylic acid displayed the best effectiveness as functional monomer, which leads to an understanding that a functional monomer is required to have both strong binding and multiple binding capacity. By choosing less polar solvents for polymerization, polymers having better retention ability and higher selectivity were obtained. Those polymers exhibited capacity factors 2 - 2.5 times as large as that for chloroform. It was also suggested that the molecular shape and size of the solvent used have influence on the resultant polymer’s binding ability.

収録刊行物

  • Analytical Sciences

    Analytical Sciences 14 (4), 699-702, 1998

    社団法人 日本分析化学会

被引用文献 (4)*注記

もっと見る

参考文献 (17)*注記

もっと見る

キーワード

詳細情報 詳細情報について

問題の指摘

ページトップへ