電炉処理ダスト中亜鉛化合物の形態別定量 Determination of Zinc Compounds in the Recovered Dusts from the Electric Furance Dusts

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The analytical methods for Zn compounds in the dust recovered from the electric furnace dust have been investigated.<BR>The recovered dust contains metallic Zn, ZnO, ZnS and trace amount of Zn(OH)<SUB>2</SUB> as Zn compounds. The sample was dissolved in the FeCl<SUB>3</SUB>-citric acid solution at room temperature. During the dissolution, metallic Zn reduced Fe(III) to Fe(II) quantitatively. The amount of Fe(II) was determined by the titration with potassium dichromate, and converted to the amount of metallic Zn. The ZnS contained in the residue was dissolved in HNO<SUB>3</SUB> (1 + 1), and the amount of Zn as ZnS was determined by ICP-AES. The amount of ZnO and Zn(OH)<SUB>2</SUB> was obtained by subtracting the amounts of metallic Zn and ZnS from the amount of total Zn.<BR>The electric furnace dust contained ZnO and ZnFe<SUB>2</SUB>O<SUB>4</SUB>, and the FeCl<SUB>3</SUB>-citric acid solution was used for the separation of ZnO from ZnFe<SUB>2</SUB>O<SUB>4</SUB>. Only ZnO was dissolved in the FeCl<SUB>3</SUB>-citric acid solution, and ZnFe<SUB>2</SUB>O<SUB>4</SUB> contained in the residue was determined by ICP-AES after alkali fusion and acid dissolution.

収録刊行物

  • 鐵と鋼 : 日本鐡鋼協會々誌

    鐵と鋼 : 日本鐡鋼協會々誌 85(2), 108-113, 1999-02

    一般社団法人 日本鉄鋼協会

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各種コード

  • NII論文ID(NAID)
    10002444585
  • NII書誌ID(NCID)
    AN00151251
  • 本文言語コード
    JPN
  • 資料種別
    ART
  • ISSN
    00211575
  • NDL 記事登録ID
    4638627
  • NDL 雑誌分類
    ZP42(科学技術--金属工学・鉱山工学--鉄鋼)
  • NDL 請求記号
    Z17-356
  • データ提供元
    CJP書誌  NDL  J-STAGE 
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