Mössbauer Study on the Phase Separation of Fe–Co–Si Alloys

  • Moriya Takeshi
    Department of Physics, Nagoya Institute of Technology
  • Ukai Kazutaka
    Department of Materials Science and Engineering, Metal Section, Nagoya Institute of Technology
  • Kato Kazuhiro
    Department of Materials Science and Engineering, Metal Section, Nagoya Institute of Technology
  • Kimura Manabu
    Department of Materials Science and Engineering, Metal Section, Nagoya Institute of Technology
  • Yazaki Kiyoshi
    Department of Materials Science and Engineering, Metal Section, Nagoya Institute of Technology
  • Isokane Y\={u}ichir\={o}
    Department of Physics, Nagoya Institute of Technology
  • Miyazaki Toru
    Department of Materials Science and Engineering, Metal Section, Nagoya Institute of Technology
  • Kozakai Takao
    Department of Materials Science and Engineering, Metal Section, Nagoya Institute of Technology
  • Koyama Toshiyuki
    Department of Materials Science and Engineering, Metal Section, Nagoya Institute of Technology

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  • Mössbauer Study on the Phase Separation of Fe–Co–Si Alloys

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Mössbauer experiments are performed on Si-rich Fe–Co–Si alloys. New information on their phase separation process, from the as-quenched state to that of the DO3+ε phases, is obtained. Analysis of the Mössbauer spectra is made based on the preferential site occupation rules. The phase boundary and the tie-line are accurately determined. The chemical order of the rapidly quenched specimen is shown to be complete inside the DO3 phase boundary, while it is incomplete outside unless annealed. The degree of the chemical order of Co atoms is determined.

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