High-Resolution TEM Observation of β-SiC Nano-Crystallite Evolution in Si-C-Ti-O Fibers Pyrolyzed from Polytitanocarbosilane Precursor
Si–C–Ti–O fibers pyrolyzed from polytitanocarbosilane polymer precursors have been observed by a high-resolution transmission electron microscope. Nano-crystalline clusters are finely dispersed in the amorphous matrices of Si–C–Ti–O fibers made from thermal-oxidation-cured and electron-irradiation-cured precursors. Nano-beam electron diffraction and simulated patterns demonstrate that these clusters are β-SiC. Such cluster formation is enhanced in the specimens heat-treated at a high temperature and cured by electron-irradiation.
- Materials transactions, JIM
Materials transactions, JIM 38(1), 5-10, 1997-01