Metastable Microstructures in Rapidly Solidified Ni Rich TiNi Alloys

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  • Metastable Microstructures in Rapidly S

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Abstract

The metastable microstructures in two rapidly solidified Ni rich Ti–Ni alloys are studied. A first report of the presence of a cubic phase with three times the lattice parameter of B2-TiNi in melt spun Ti40Ni60 alloy is presented. This phase has precipitated from the massively solidified B2-TiNi. We also report the formation of a faulted structure (A9), polytypic to TiNi3 along with TiNi3 in melt spun Ti30Ni70 alloy. It is argued that this structure is stabilised due to a specific valence electron by atom ratio.

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