Solidification and Structural Characteristics of α(Al)–Mg<SUB>2</SUB>Si Eutectic

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  • Solidification and Structural Characteristics of α(Al)-Mg2Si Eutectic
  • Solidification and Structural Character
  • Solidification and Structural Characteristics of &alpha;(Al)&ndash;Mg<SUB>2</SUB>Si Eutectic

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Abstract

Solidification and structural characteristics of α(Al)–Mg2Si eutectic in the Al–Mg–Si system were investigated by thermoanalysis and directional solidification techniques. The two-phase eutectic line of L⇔α(Al)+Mg2Si, the temperature-change section of a pseudobinary α(Al)–Mg2Si system and the eutectic coupled zone within this section have been measured accurately. It was demonstrated that the coupled zone in the pseudobinary α(Al)–Mg2Si system could be described as C=1.35×103V+C0, where C is the molar percentage of Mg2Si, V is the solidification velocity in m/s, C0 is the molar percentage of Mg2Si when the eutectic structure is obtained through a near-equilibrium solidification, and 3.65 mol%<C0<5.0 mol%. In this system, Mg2Si is the nucleating and leading phase during eutectic growth, and the primary crystals exhibits a morphology of regular hexahedron with {100} faces. In the eutectic alloy, the morphology of phase Mg2Si transforms from lamellae to rods when the solidification velocity is higher than 1.1×10−5 m/s. The relationship between the lamellar or interrod spacing, λ of eutectic Mg2Si and the solidification velocity, V, fits the equation<BR>λ1.93V=7.1×10−17G−0.414<BR>where G is the temperature gradient ahead of the solid-liquid interface in the melt, which is in K/m, λ is in m and V is in m/s.

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