Magnetic Analysis of Precipitation and Coarsening of Carbides in Steels.

  • Hildebrand Helga
    Institute of Physical Metallurgy, Freiberg University of Mining and Technology

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Dispersion microstructures in C-, Cr- and Mn-alloyed steels result from the precipitation and coarsening of carbide particles from the martensitic initial condition. The changes in the microstructure were observed at aging temperatures T=500, 600, 650 and 700°C and for the time t=1 to 4290 min by measuring the coercive field strength HC. The particle size analysis on scanning electron micrographs of M3C in the steels and of M6C (+MC) carbide particles in the case of the high-alloyed steel X80WMo6.5 yielded to a certain connection with HC. Thus HC can be taken as an indirect microstructural characteristic quantity insteed of directly observed microstructure data.<br>It was found that nucleation, growth and the dominating coarsening of the particles take place permanently in so-called generations. With increasing time the particle sizes in the one after another following generations become smaller because of the matrix depletion of the participated elements by precipitation. The Ostwald-ripening law is to apply separately to each generation. All the processes and relationships, which are connected with HC, can be written mathematically.

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