Small-angle Neutron Scattering Measurements on SnO2 Particles Suspended in Liquid Sn-S Systems.

  • Iida Takamichi
    Department of Materials Science and Processing, Faculty of Engineering, Osaka University
  • Kita Yoshifumi
    Department of Materials Science and Processing, Faculty of Engineering, Osaka University
  • Umesaki Norimasa
    Material Physics Department, Government Industrial Research Institute
  • Kamijo Nagao
    Material Physics Department, Government Industrial Research Institute
  • Misawa Masakatsu
    Department of Chemistry, Faculty of Science, Niigata University
  • FURUSAKA Michihiro
    National Laboratory for High Energy Physics

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Small-angle neutron scattering measurements were carried out on liquid Sn-0.4mol%SnO2 (solid spherical particle)-1.1at%S, Sn-0.4mol%SnO2 and Sn-1.1at%S systems at 723 K. The scattering intensity for Sn-SnO2 system is proportional to the parameter, Q-4, while the scattering intensity for Sn-SnO2-S system is lower, showing nearly Q-3 dependence. To analyze them, the scattering intensity has been calculated for Sn-SnO2 and Sn-SnO2-S systems with various particle sizes and thicknesses of the surface layer. For Sn-SnO2-S system, the best fit with the experimental data has been obtained for a particle size of 4μm and the surface layer thickness of 100 Å, consisting of S.

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