Thermodynamic Analysis of Binary and Ternary Silicate Systems by a Structural Model

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A critical evaluation of the thermodynamic properties as well as the phase diagrams for the systems MgO-SiO<sub>2</sub> and FeO-SiO<sub>2</sub> is performed with a structural model and for the systems MnO-MgO, FeO-MnO and FeO-MgO through the regular solution model.<br> The structural model for binary silicate melts is now extended to ternary systems. It is shown that, for systems SiO<sub>2</sub>-AO-BO, random mixing of cations A<sup>2+</sup> and B<sup>2+</sup> occurs when the oxides AO and BO behave in a similar way with silicate. If the AO-SiO<sub>2</sub> and BO-SiO<sub>2</sub> binary systems exhibit similar thermodynamic behavior, that is comparable free energies of mixing, the properties of the ternary SiO<sub>2</sub>-AO-BO can be extrapolated from those binary systems in a straightforward fashion. This condition is found in simple silicates such as SiO<sub>2</sub>-MnO-MgO, SiO<sub>2</sub>-FeO-MnO and SiO<sub>2</sub>-FeO-MgO systems where the activities and liquidus temperatures calculated solely from data on the binary sub-systems are in good agreement with measured ternary data.

収録刊行物

  • ISIJ international

    ISIJ international 39(5), 399-408, 1999-05-15

    The Iron and Steel Institute of Japan

参考文献:  24件中 1-24件 を表示

  • <no title>

    FINCHAM C. J. B.

    Proc. R. Soc. A223, 40, 1954

    被引用文献3件

  • <no title>

    LIN P. L.

    Metall. Trans. B 10B, 667, 1979

    被引用文献5件

  • <no title>

    PELTON A. D.

    Metall. Trans. B 24B, 817, 1992

    被引用文献2件

  • <no title>

    BOWEN N. L.

    Am. J. Sci. 1, 487, 1914

    被引用文献1件

  • <no title>

    GREIG J. W.

    Am. J. Sci. 13(1), 133), 1927

    被引用文献1件

  • <no title>

    GREIG J. W.

    Am. J. Sci. 14, 473, 1927

    被引用文献1件

  • <no title>

    OL'SHANSKII Y. I.

    Dokl. Akad. Nauk SSSR 76, 93, 1951

    被引用文献1件

  • <no title>

    HAGEMAN V. B. M.

    Phys. Chem. Glasses 27, 194, 1986

    被引用文献2件

  • <no title>

    REIN R. H.

    Trans. Metall. Soc. AIME 223, 415, 1965

    被引用文献1件

  • <no title>

    BOWEN N. L.

    Am. J. Sc. 24, 177, 1932

    被引用文献1件

  • <no title>

    SCHUHMANN R.

    J. Met. 3, 401, 1951

    被引用文献2件

  • <no title>

    ALLEN W. C.

    J. Am. Ceram. Soc. 38, 264, 1955

    被引用文献1件

  • <no title>

    DISTIN P. A.

    Can. Metall. Q. 10, 73, 1971

    被引用文献1件

  • <no title>

    SCHENCK H.

    Arch. Eisenhuttenwes 35, 269, 1964

    被引用文献1件

  • <no title>

    SCHENCK H.

    Arch. Eisenhuttenwes 32, 741, 1961

    被引用文献1件

  • <no title>

    SRECEC I.

    Phys. Chem. Miner. 14, 492, 1987

    被引用文献1件

  • <no title>

    FISHER W. A.

    Arch. Eisenhuttenwes 32, 1, 1961

    被引用文献1件

  • <no title>

    SCHERDTFEGER K.

    Trans Met. Soc. AIME 239, 1114, 1967

    被引用文献1件

  • <no title>

    GLASSER F. P.

    J. Am. Ceram. Soc. 43, 135, 1960

    被引用文献1件

  • <no title>

    RIBOUD P. V.

    Trans. AIME 224, 28, 1962

    被引用文献1件

  • <no title>

    BAN-YA S.

    Tetsu-to-Hagane 73, 476, 1987

    被引用文献6件

  • <no title>

    OSBORN E. F.

    Phase Equilibrium Diagrams of Oxide Systems, 1960

    被引用文献4件

  • <no title>

    BOWEN N. L.

    Am. J. Sci. 29, 157, 1935

    被引用文献1件

  • <no title>

    ROMERO-SERRANO A.

    Metall. Trans. B 26B, 305, 1995

    DOI 被引用文献2件

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