パルス電解ストップトフロー法による電解生成活性種の反応解析 Pulse-Electrolysis Stopped-Flow Method for Spectroscopic Analyses of Reaction Processes Involving Electrogenerated Species

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著者

    • 小山 宗孝 OYAMA Munetaka
    • 京都大学大学院工学研究科 Department of Material Chemistry, Graduate School of Engineering, Kyoto University

抄録

By connecting a column electrolysis method with a stopped-flow technique, a pulse-electrolysis stopped-flow method has been developed. This method has many advantages that it can be applied to the detection and characterization of unstable intermediates as well as the analysis of the reaction kinetics of heterogeneous electrode reactions as homogeneous reactions. In addition, this method can be utilized combined with various spectroscopic methods including UV-visible, resonance Raman (RR) and electrogenerated chemiluminescence (ECL) measurements. In this review, the advantages of this method are demonstrated with many successful results in the analyses of the reaction kinetics and mechanisms involving electrogenerated species obtained by using the pulse-electrolysis stopped-flow method.

収録刊行物

  • ポーラログラフィー  

    ポーラログラフィー 45(1), 2-16, 1999-05-20 

    日本ポーラログラフ学会

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各種コード

  • NII論文ID(NAID)
    10002466820
  • NII書誌ID(NCID)
    AN00093235
  • 本文言語コード
    JPN
  • 資料種別
    REV
  • ISSN
    0034-6691
  • NDL 記事登録ID
    4735867
  • NDL 雑誌分類
    ZP4(科学技術--化学・化学工業--分析化学)
  • NDL 請求記号
    Z17-150
  • データ提供元
    CJP書誌  NDL  J-STAGE 
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