還元剤として過酸化水素および亜硫酸ナトリウムを用いたコバルトリッチクラストの塩酸浸出 Hydrochloric Acid Leaching of Cobalt-Rich Ferromanganese Crust using Hydrogen Peroxide and Sodium Sulfite as Reducing Agents

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Hydrochloric acid leaching of Co, Ni, Cu, Mn and Fe from the cobalt-rich ferromanganese crust under reducing conditions was performed using hydrogen peroxide and sodium sulfite as reducing agents. Hydrochloric acid concentration more than 3.0 mol/dm3 is required to obtain the high extraction of Co and Ni without reducing agents at ambient temperature. The high extraction of Cu in dilute hydrochloric acid solution without reducing agents at ammbient temperature explains the different form of Cu from other metals present in cobalt-rich ferromanganese crusts. When hydrogen peroxide or sodium sulfite was used as reducing agent, the high extraction of Co and Ni was obtained with dilute hydrochloric acid at ambient temperature. In particular, hydrogen peroxide extracts metals in stoichiometric amounts. The extraction of Ni depends significantly on the leaching temperature, regardless of the presence or absence of reducing agents.資源・素材学会(http://www.jstage.jst.go.jp/browse/shigentosozai/_vols/-char/ja)

Hydrochloric acid leaching of Co, Ni, Cu, Mn and Fe from the cobalt-rich ferromanganese crust under reducing conditions was performed using hydrogen peroxide and sodium sulfite as reducing agents. Hydrochloric acid concentration more than 3.0 mol/dm3 is required to obtain the high extraction of Co and Ni without reducing agents at ambient temperature. The high extraction of Cu in dilute hydrochloric acid solution without reducing agents at ammbient temperature explains the different form of Cu from other metals present in cobalt-rich ferromanganese crusts. When hydrogen peroxide or sodium sulfite was used as reducing agent, the high extraction of Co and Ni was obtained with dilute hydrochloric acid at ambient temperature. In particular, hydrogen peroxide extracts metals in stoichiometric amounts. The extraction of Ni depends significantly on the leaching temperature, regardless of the presence or absence of reducing agents.

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  • 資源と素材 : 資源・素材学会誌 : journal of the Mining and Materials Processing Institute of Japan  

    資源と素材 : 資源・素材学会誌 : journal of the Mining and Materials Processing Institute of Japan 115(1), 29-34, 1999-01-25 

    資源・素材学会

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各種コード

  • NII論文ID(NAID)
    10002468972
  • NII書誌ID(NCID)
    AN10062646
  • 本文言語コード
    JPN
  • 資料種別
    ART
  • ISSN
    09161740
  • NDL 記事登録ID
    4640278
  • NDL 雑誌分類
    ZP41(科学技術--金属工学・鉱山工学)
  • NDL 請求記号
    Z17-315
  • データ提供元
    CJP書誌  NDL  IR  J-STAGE 
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