Solidification Behavior and a Quasi-Ternary Phase Diagram of the YBCO/Ag System

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  • YBCO/Ag系の擬3元状態図と凝固挙動
  • YBCO Agケイ ノ ギ3ゲン ジョウタイズ ト ギョウコ キョドウ

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Abstract

It is necessary to understand the solidification behavior because the mechanical properties and the thermal conductivity of the YBCO/Ag superconducting current leads prepared by unidirectional solidification method are influenced by the silver particle dispersion. Solidification behavior in the YBCO/Ag superconductor is discussed with the Y2Ba1Cu1O5-Ba3Cu5Ox-Ag (211-035-Ag) quasi-ternary phase diagrams, which were constructed by the analyzes of the solute compositions in the melt. The obtained phase diagram indicates that the solidification of the YBCO/Ag system proceeds through the monotecto-peritectic reaction, expressed as 211+BaO-CuO-rich melt (L1)→Y1Ba2Cu3Oy(123)+Liquid metallic silver (L2). The diffusion fields in the YBCO/Ag system were discussed with using this phase diagram.

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