静電噴霧法（ESD）により作製したリチウム複合酸化物薄膜の溶融炭酸塩中での安定性

• 山田 耕太

  東北大学素材工学研究所

• 佐藤 修彰

  東北大学素材工学研究所

• 藤野 威男

  東北大学素材工学研究所

• 西澤 松彦

  東北大学大学院工学研究科

• 内田 勇

  東北大学大学院工学研究科

書誌事項

タイトル別名

• Preparation of Li Containing Mixed Metal Oxide Films by Electrostatic Spray Deposition and Their Stabilities in Molten Alkali Carbonates
• セイデン フンムホウ ESD ニ ヨリ サクセイ シタ リチウム フクゴウ サンカブツ ハクマク ノ ヨウユウ タンサンエン チュウ デ ノ アンテイセイ

抄録

LiCo_0.5Ni_0.5O₂, LiAl_0.25Ni_0.75O₂ and Li₄Mn₅O1₂ films were prepared by electrostatic spray deposition (ESD) onto gold substrates, and thelr stabilities in (62+38) mol% (Li+K) CO₃ at 923K under an oxidant gas condition were investigated by XRD and EDX techniques. XRD measurements revealed that after immersion in the melt, the LiCo_0.5Ni_0.5O₂ maintained the hexagonal structure, while the cubic phase of Li₄Mn₅O₁₂ changed to a monoclinic of Li₂MnO₃. The XRD pattern of LiAl_0.25Ni_0.75O₂ showed low crystallinity. The atomic ratios of Co/Ni and Al/Ni in the Ni-containing oxide films were found to be increased after immersion in the melt by EDX analysis, indicating that the nickel partly dissolved into the melt. The oxygen reduction currents at all the films were observed by cyclic voltammetry. It showed that the use of manganese is also hopeful as a cathode material of MCFC.

収録刊行物

• Electrochemistry

  Electrochemistry 67 (1), 68-71, 1999-01-05

  公益社団法人　電気化学会

キーワード

• Electrostatic Spray Deposition
• Thin Film
• Molten Carbonate
• Cathode

詳細情報

• CRID: 1390282752370151168
• NII論文ID: 10002566166
• NII書誌ID: AN00151637
• DOI: 10.5796/electrochemistry.67.68
• ISSN: 21862451
• ISSN: 13443542
• NDL書誌ID: 970684
• Web Site: https://ndlsearch.ndl.go.jp/books/R000000004-I970684
• Web Site: https://www.jstage.jst.go.jp/article/electrochemistry/67/1/67_68/_pdf
• 本文言語コード: ja
• データソース種別:
  • JaLC
  • NDL
  • Crossref
  • CiNii Articles
• 抄録ライセンスフラグ: 使用可